Chemical Engineering Thermodynamics

232. In an ideal solution, the activity of a component equals its

  1. Mole fraction
  2. Fugacity at the same temperature and pressure
  3. Partial pressure
  4. None of these

Correct answer: (A)
Mole fraction

233. In an irreversible process

  1. Tds = dE - dW = 0
  2. dE - dW - Tds = 0
  3. Tds - dE + dW < 0
  4. Tds - dT + dW < 0

Correct answer: (C)
Tds - dE + dW < 0

234. In an isothermal process on an ideal gas, the pressure increases by 0.5 percent. The volume decreases by about _________ percent.

  1. 0.25
  2. 0.5
  3. 0.75
  4. 1

Correct answer: (B)
0.5

235. In any spontaneous process,

  1. Only F decreases
  2. Only A decreases
  3. Both F and A decreases
  4. Both F and A increase

Correct answer: (C)
Both F and A decreases

236. In any spontaneous process, the _________ free energy decreases.

  1. Helmholtz
  2. Gibbs
  3. Both ‘a’ & ‘b’
  4. Neither 'a' nor 'b'

Correct answer: (C)
Both ‘a’ & ‘b’

237. In case of a close thermodynamic system, there is _________ across the boundaries.

  1. No heat and mass transfer
  2. No mass transfer but heat transfer
  3. Mass and energy transfer
  4. None of these

Correct answer: (B)
No mass transfer but heat transfer

238. In case of a reversible process (following pvn = constant), work obtained for trebling the volume (v1 = 1 m3 and v23 m3) is maximum, when the value of 'n' is

  1. 0
  2. 1
  3. y = 1.44
  4. 1.66

Correct answer: (A)
0

239. In case of an _________ process, the temperature of the system increases.

  1. Isothermal compression
  2. Isothermal expansion
  3. Adiabatic expansion
  4. Adiabatic compression

Correct answer: (D)
Adiabatic compression

240. In case of steady flow compression polytropic process (PVn = constant), the work done on air is the lowest, when

  1. n = y = 1.4
  2. n = 0
  3. n = 1
  4. n = 1.66

Correct answer: (C)
n = 1

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